Technical Track 2008

Thursday, September 11th, 09:30 – 18:00 h

 

Moderator:


Dr. Patrick Vandereecken

Performance
Adhesive & Sealant Specialist, Dow Corning Europe S.A.

Fumed Metal Oxides and Silanes in Hot Melt Pressure Sensitive Adhesives

Dr. Thomas Schlosser
Head of Applied Technology "Adhesives and Sealants", Evonik Degussa GmbH 
Fumed metal oxides and silanes have long been known to improve the performance of chemically curing and solvent-based adhesives and sealants. This paper discusses the improvements seen in hot melt adhesives when using those products. In particular, the unexpected improvements of heat stability when using a particular fumed metal oxide and its derivatives; and the reduction in viscosity when silanes are used. The benefits of choosing a specific fumed metal oxide or silane is discussed, and their impact on the adhesive properties.

 

Optimizing the Performances of a Mixed Elastomer PSA - Reducing System Costs by Replacing SBS for SIS in Hot Melt PSA Systems

Alain Martinet
Technical Manager, Cray Valley 
Along with the increasing raw material costs there is the increasing pressures to develop adhesive systems with reduced system costs. One way to reduce the system costs of a hot melt pressure sensitive adhesive coated tape is through the use of less expensive butadiene-containing elastomers to reduce the amount of SIS that is used. This paper describes the development of a new hydrocarbon resin which achieves new levels of compatibility for such resins more polar elastomers such as SBS and other butadiene-containing elastomers. The development of the resin will reviewed as well as Experimental Designs (DOE) which will demonstrate how the performance of the PSA can be optimized to achieve optimum Peel Adhesion, Tack, Shear and all at a reduced cost.

The following Contour Plot is one example of how the Loop Tack off of Stainless Steel is affected by varying concentrations of tackifier resin and SIS content.

 

Delivering Beyond Adhesion… Solutions!": Innovations in Metallocene Polymers and the Future of the Adhesives Industry

Allan McLennaghan
Application Technology Leader, Dow Europe GmbH 
Metallocene polymers over the past decade have seen tremendous utility and growth in the hot melt adhesives industry.  Starting their roots in packaging applications, Metallocene polymers are now expanding into areas such as pressure sensitive adhesives for nonwovens and labels.  Working together with the formulators, this technology is gaining speed and offering limitless possibilities.  This presentation will share the historical view of the evolution of Metallocene polymers and their penetration into the adhesives market. Dow continues to be the pioneer in metallocene technology for adhesives by harnessing its high throughput catalyst development, which enables our fast introduction of novel technologies which are expanding and challenging the traditional uses of polyolefins. This presentation will also preview the next generation Metallocene polymers designed to meet market trends and industry needs.
Selim Yalvac
Global Development Leader, The Dow Chemical Company
 

A New Improved Silylated Polymer Range for Sealants and Adhesives

Dr. Luc Peeters
Technical Manager, Kaneka Belgium 
Methoxy silylated polymers, such as MS-Polymers, are already long known for their green properties. These polymers enable the formulation of isocyanate free and low VOC sealants and adhesives. Examples of such products can be found in several application fields, such as adhesives for different flooring and roofing materials, and will be discussed.
To further enhance the overall properties and broaden the formulation matrix a new generation of MS-Polymers was developed. With these new polymers the formulation of faster curing sealants and adhesives will be possible and moreover properties as for instance elastic recovery will be improved.

 

Another Step Ahead with GENIOSIL® STP-E for Elastic Adhesives & Sealants

Dr. Wolfram Schindler
Technical Service Manager, Wacker Chemie AG 
WACKER’s new range of silyl-terminated binders – GENIOSIL® STP-E - includes swift curing alpha-silane terminated grades. The unique silylation chemistry of these prepolymers ensures reliable binder quality.
Hybrid technologies are not new in the market. Yet it is often a challenge to couple suitable cure speed with the industrial requirements for good bonding and mechanical properties. GENIOSIL® STP-E can be easily formulated into products yet delivers that desirable balance of mechanical strength, swift cure and environmentally–optimized formulation ingredients.
GENIOSIL® STP-E prepolymers have found already extensive use in different applications like construction adhesives, wood flooring adhesives, industrial elastic adhesives and DIY product.

 

Silica Nanoparticles – Powerful Raw Materials for Adhesives

Dr. Stephan Sprenger
BU Manager Adhesives & Composites Materials, RLP, Nanoresins AG 
One and two part epoxy adhesives are used in many different industrial applications, from automotive to aerospace, from shipbuilding to bridge repair systems, LNG transportation ships or wind-turbine blades.

State-of-the-art epoxy adhesives are usually rubber toughened. The addition of surface modified silica nanoparticles improves several adhesive properties: modulus, stiffness, compression strength and lap shear strength are increased. Toughness is increased significantly, and fatigue behaviour is improved as well. "Hybrid" adhesives based on this synergy are already commercially available.

With the silica nanoparticles available in industrial quantities in acrylic monomers or solvents as well, this technology is not limited to epoxy adhesives only.

 

NEW PU-Raw Materials for Adhesives and Sealants without R 40 Labeling

Dr. Mathias Matner
Senior Manager, Bayer MaterialScience AG 
MDI containing preparations (>1% MDI) most probably have to be labeled as carcinogen category 3 (R 40; limited evidence of carcinogenic effect) by mid 2009. This creates a market need for PU-based adhesives and sealants without the need for R 40 labeling, regardless the fact that there is no evidence of cancer when occupational exposure limits are observed.
One way to achieve this objective is to use specially designed prepolymers to formulate adhesives and sealants with a low free monomer content and low emission properties. Bayer MaterialScience is developing tailor-made prepolymers based on special isocyanates and technologies  for a wide range of polyurethane adhesive and sealant applications.
A second approach is the combination of polyurethane technology with silane-based cross linking. This method combines the excellent mechanical properties of the polyurethane backbone with the bubble free moisture cure delivered by the silane curing mechanism.

 

Nano-Rheology of Dioctylphtalate Confined between Surfaces Modified with Long Hydrocarbon Chains

Dr. Yoshisada Kayano
Technical Manager, Shiraishi Kogyo Kaisha Ltd. 
Nano-particles are widely used as materials to improve rheological properties of adhesives/sealants. But scientific explanations of the high viscosity have been unclear up to now. Nano-particles of calcium carbonate are empirically modified on the surfaces with fatty acid to increase the viscosity of their dispersions. Based on the knowledge that precipitated calcium carbonate creates high viscosity in dioctylphtalate, the viscosity of dioctylphtalate in a nanometer space was investigated using the shear resonance measurement. We will explain the nano-material technology and knowledge of application for sealants formulations.

 

A Low-Formaldehyde Content Wood Adhesive Without Bondline Chromatic Alteration

Dr. Fabio Chiozza
Adhesive and Textile Department Manager, Vinavil S.p.A. 
Actual trends in launching new formulates based on vinylacetate dispersionsusable for water-resistant adhesives for wood and wood-based products concern glues with zero formaldehyde.
Moreover, another peculiar behaviour of this class of adhesives is the chromatic alteration of the bondline during time, which could represent an aesthetic defect for some specific products (panels, furniture etc.). This paper demonstrates that it is possible to satisfy market needs by a new approach in formulating products with excellent performances,low formaldehyde emission and no coloration of the glueline, mainly if compared with traditional PVAc dispersions used for the same applications.

 

CDM, Controlled Delaminating Materials

Dr. Carl-Ola Danielsson
CDM Specialist, Stora Enso Research Centre Karlstad 
Controlled delaminating materials, CDM, introduce new exciting solutions in the packaging
industry. The technology has the potential to save cost in distribution through significantly shorter handling time when transferring products from distribution packaging to store shelves. It also gives the possibility for new consumer packaging with easy opening, product presentation, theft prevention, authenticity etc. The presently available CDM applications are based on electrically debondable adhesives. In this talk the development of electrically debondable adhesive is presented.

 

Modern Waterborne Adhesives Based on Polyurethanes and Polychloroprenes

Dr. Martin Vollmer
Vice President, Bayer MaterialScience AG 
Markets for waterborne adhesive dispersions are continuously growing for many years, mainly driven by innovation in raw materials, formulation and application know-how as well as the need for eco-friendly solutions.
Latest developments in waterborne adhesive raw materials by Bayer MaterialScience AG such as the new 1-component latent reactive Polyurethane dispersions offer advanced performance combined with simplified bonding processes, e.g. via pre-coated, substrates which can be activated upon heating. Our new improved Polychloroprene dispersions with very low VOC levels for direct use in efficient foam bonding processes are latest examples to set trends in environmentally friendly adhesive technologies.

 

New Thermoplastic Polyurethane (TPU) for Adhesives from Renewable Sources

Jean-Marc Galvez
Commercial Manager, Merquinsa 
There is a clear trend in the end markets towards sustainable chemical products that minimize the use of petrochemical resources without limiting functionalities, quality and economics of currently used products and, if possible, adding new functionalities to them.
A polyurethane-based polymer is the result of the chemical reaction of one or several polyols, and one or several isocyanates. Polyols derived from vegetal sources are well known in the polyurethane technology. Nevertheless, the use of such polyols has been limited to foam or coating applications due to their inherent and difficult to control polyfunctionality. Because high-performance polyurethane adhesives show excellent mechanical and elastomeric properties, the first target of our research was to obtain strictly bifunctional polyols derived from renewable vegetal sources.
A new family of TPU for adhesives are presented. This new TPU series has application for polyurethane solvent and water based adhesives, polyurethane for thermobonding and shoe stiffeners, and polyurethane reactive hot-melt adhesives. A full range of vegetal source derived bifunctional polyols has been developed. The reaction of these polyols in the TPU formulation allows new TPUs with a renewable content ranging from 30% to 90% by weight. Compared to the standard petrochemical based grades, the new ‘green-TPUs’ show better hydrolytic resistance and green strength, allow higher productivity, and maintain equivalent mechanical properties. For instance, the retention of mechanical properties after a tropical test at 80ºC for one month increases from 25% to 75%. A very important improvement in crystallization properties is also observed, with crystallization speed increase of 50% and crystallization enthalpy increase of 30%.

 

Proceedings

Venue


Palais du Pharo
58 boulevard Charles Livon
13233 Marseille Cedex 20
France

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