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There is a clear trend in the end markets towards sustainable chemical products that minimize the use of petrochemical resources without limiting functionalities, quality and economics of currently used products and, if possible, adding new functionalities to them.
A polyurethane-based polymer is the result of the chemical reaction of one or several polyols, and one or several isocyanates. Polyols derived from vegetal sources are well known in the polyurethane technology. Nevertheless, the use of such polyols has been limited to foam or coating applications due to their inherent and difficult to control polyfunctionality. Because high-performance polyurethane adhesives show excellent mechanical and elastomeric properties, the first target of our research was to obtain strictly bifunctional polyols derived from renewable vegetal sources.
A new family of TPU for adhesives are presented. This new TPU series has application for polyurethane solvent and water based adhesives, polyurethane for thermobonding and shoe stiffeners, and polyurethane reactive hot-melt adhesives. A full range of vegetal source derived bifunctional polyols has been developed. The reaction of these polyols in the TPU formulation allows new TPUs with a renewable content ranging from 30% to 90% by weight. Compared to the standard petrochemical based grades, the new ‘green-TPUs’ show better hydrolytic resistance and green strength, allow higher productivity, and maintain equivalent mechanical properties. For instance, the retention of mechanical properties after a tropical test at 80ºC for one month increases from 25% to 75%. A very important improvement in crystallization properties is also observed, with crystallization speed increase of 50% and crystallization enthalpy increase of 30%. |